data_global
_chemical_name_mineral 'Cobaltoblodite'
loop_
_publ_author_name
'Kasatkin A V'
'Nestola F'
'Plasil J'
'Marty J'
'Belakovskiy D I'
'Agakhanov A A'
'Mills S J'
'Pedron D'
'Lanza A'
'Favaro M'
'Bianchin S'
'Lykova I S'
'Golias V'
'Birch W D'
_journal_name_full 'Mineralogical Magazine'
_journal_volume 77
_journal_year 2013
_journal_page_first 367
_journal_page_last 383
_publ_section_title
;
 Manganoblodite, Na2Mn(SO4)2*4H2O, and cobaltoblodite, Na2Co(SO4)2*4H2O: two new
 members of the blodite group from the Blue Lizard mine, San Juan County, Utah, USA
;
_database_code_amcsd 19856
_chemical_compound_source 'Blue Lizard mine, San Juan County, Utah, USA'
_chemical_formula_sum 'Na2 Co.36 Mg.3 Mn.17 Ni.12 S2 O12 H8'
_cell_length_a 11.147
_cell_length_b 8.268
_cell_length_c 5.5396
_cell_angle_alpha 90.0
_cell_angle_beta 100.517
_cell_angle_gamma 90.0
_cell_volume 501.971
_exptl_crystal_density_diffrn  2.349
_symmetry_space_group_name_H-M 'P 1 21/a 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2-y,z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Na   0.36203  0.07052  0.12983  1.0  0.0235
Co   0.0  0.0  0.0  0.36  0.01592
Mg   0.0  0.0  0.0  0.3  0.01592
Mn   0.0  0.0  0.0  0.17  0.01592
Ni   0.0  0.0  0.0  0.12  0.01592
S   0.13624  0.28981  0.37043  1.0  0.01457
O1   0.26554  0.27159  0.3473  1.0  0.0237
O2   0.07923  0.4172  0.2079  1.0  0.0255
O3   0.07173  0.1355  0.3131  1.0  0.0245
O4   0.13185  0.3297  0.6293  1.0  0.0245
O5   0.1626  0.0382  0.872  1.0  0.0206
O6   0.08181  0.7872  0.1784  1.0  0.0219
H5A   0.164  0.114  0.794  1.0  0.08
H5B   0.174  -0.042  0.785  1.0  0.08
H6A   0.039  0.731  0.232  1.0  0.08
H6B   0.125  0.796  0.304  1.0  0.08
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Na   0.0203  0.0232  0.0264  0.001  0.0027  -0.0007
Co   0.0152  0.0151  0.0175  -0.00108  0.00302  -0.00065
Mg   0.0152  0.0151  0.0175  -0.00108  0.00302  -0.00065
Mn   0.0152  0.0151  0.0175  -0.00108  0.00302  -0.00065
Ni   0.0152  0.0151  0.0175  -0.00108  0.00302  -0.00065
S   0.0145  0.0148  0.01413  -0.00074  0.00179  0.00056
O1   0.0152  0.025  0.0313  0.0024  0.0056  0.0028
O2   0.0198  0.0269  0.0293  0.0036  0.0032  0.0115
O3   0.0303  0.0221  0.021  -0.0106  0.0046  -0.0039
O4   0.0341  0.0232  0.0171  -0.0024  0.0074  -0.0043
O5   0.0216  0.0203  0.0209  0.0003  0.0065  0.0014
O6   0.0222  0.019  0.0222  -0.0017  -0.0017  0.0008